1.

The standard reduction potential for `Fe^(2+) //Fe` and `Sn^(2+) //Sn` electrodes are `-0.44` and `-0.14 ` volt respectively. For the given cell reaction `Fe^(2+) + Sn rarr Fe + Sn^(2+) `, the standard ` EMF` is.A. ` -0 . 30 V`B. ` -0 . 58 V`C. ` +0. 58 V`D. ` + 0. 3 0 V`

Answer» Correct Answer - A
For the cell reaction.Fe acts as cathode and Sn as anode, Hence,
`E_("cell")^2 -E_("cathode")^2 -E_("anode")^@ =- 0.44-(-0.14) =- 0.30 V`
The negative EMF suggests that the reaction goes spontaneously in reversed direction.


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