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The sulphide ion concentration `[S^(2-)]` in saturated `H_(2)S` solution is `1 xx 10^(-22)`. Which of the following sulphides should be quantitatively precipitated by `H_(2)S` in the presence of dil. HCl `{:("Sulphide",,"Solubility Product"),("(I)",,1.4xx10^(-16)),("(II)",,1.2xx10^(-22)),("(III)",,8.2xx10^(-46)),("(IV)",,5.0xx10^(-34)):}`A. I, IIB. III, IVC. II, III, IVD. Only I |
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Answer» Correct Answer - B Basic radicals of group II & IV are precipitated by `H_(2)S` in the form of their sulphides. Iind group in acidic medium & IV group in alkaline medium. They precipitate when ionic product increases than solubility product. |
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