1.

The sulphide ion concentration `[S^(2-)]` in saturated `H_(2)S` solution is `1xx10^(-22)`. Which of the following sulphides should be quantitavely precipitated by `H_(2)S` in the presence of dil. `HCl`? `{:("Sulphide",,"Solubility Product"),((I),,1.4xx10^(16)),((II),,1.2xx10^(-22)),((III),,8.2xx10^(-46)),((IV),,5.0xx10^(-34)):}`A. I,IIB. III,IVC. II,III,IVD. Only I

Answer» Correct Answer - B
Basis radials of group II & IV are precipitated by `H_(2)S` in the form of their sulhphides. Iind group in acidic medium & IV
group in acidic medium & IV
group in alkaline medium. They precipitate when ionic product increases than solubility product.


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