1.

The synthesis of higher alkyne from lower alkyne is achieved by adding a bromo alkane in to amixture of Sodium amide and an alkyne. Which of the following combination(s) of bromoalkane and alkyne, can lead to the formation of 3-Octyne.

Answer»

1-bromo pentane and propyne
1-bromo butane and butyne-2
1-bromo butane and butyne-1
1-bromopropane and pentyne-1

Solution :The above REACTION is possible only with terminal (acidic) alkynes. Hence option "B". is not CORRECT as it is non-terminal alkyne


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