The system shown in the figure is in equilibrium, where A and B are isomeric liquids and form an ideal solution at TK. Standard vapour pressures of A and B are P_(A)^(0) and P_(B)^(0), respectively, at TK. We collect the vapour of A and B in two containers of volume V, first container is maintained at 2 T K and second container is maintained at 3T//2. At the temperature greater than T K, both A and B exist in only gaseous form. We assume than collected gases behave ideally at 2 T K and there may take place an isomerisation reaction in which A gets converted into B by first-order kinetics reaction given as: Aoverset(k)rarrB, where k is a rate constant. In container (II) at the given temperature 3T//2, A and B are ideal in nature and non reacting in nature. A small pin hole is made into container. We can determine the initial rate of effusion of both gases in vacuum by the expression r=K.(P)/(sqrt(M_(0))) where P= pressure differences between system and surrounding K= positive constant M_(0)= molecular weight of the gas If vapours are collected in a container of volume 8.21 L maintained at 3 T//2K, where T=50 K, then the ratio of initial rate of effusion of gases A and B is given as