1.

The total energy of an electron in the first excited state of the hydrogen atom is about -3.4 eV. Which of the answers above would change if the choice of the zero of potential energy is changed?

Answer» We know kinetic energy of electron
`=(Kze^(2))/(2r)`
and P.E of electron `=(-Kze^(2))/(r)`
P.E.=-2 (kinetic energy)
In this calculation electric potential and hence potential energy is zero at infinity. Total energy = PE + KE = -2KE + KE = -KE
If zero of potential energy is changed, KE does not change and continues to be + 3.4 eV. However, the P.E. and total energy of the state would change with the choice of zero of potential energy.


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