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The van der Waal's equation of state for 1 mole real gas is (P + (a)/(V^(2))) (v - b) = RT....(i) The Virial equation for 1 mole real gas is PV = RT [1 + (x)/(V) + (y)/(V^(2)) + (z)/(V^(3))+....." To higher power of " V] ....(ii) when x, y and z are constants which are known as 2nd, 3rd adn 4th co-efficients respectively. The temperature at which real gas obeys ideal gas equation i.e., (PV = nRT) is known as Boyle's temperature. Answer the following questions on the basis of the above write up : If equation (ii) can be one of the way of writing of equation (i), then what will be the value of y? |
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Answer» `B - (a)/(RT)` |
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