1.

The vapour pressure of chloroform `(CHCl)_(3)` and dichlorocethene `(CH_(2)Cl_(2))` at `298 K` is `200 mm Hg ` and `415 mm Hg`, respectively. Calculate a. The vapour pressure of the solution prepared by mixing `25.5 g` of `CHCl_(3)` and `40 g` of `CH_(2)_Cl(2)` at `298 K`. b. Mole fractions of each components in vapour phase .A. 90.92 mm HgB. 615.0 mm HgC. 347.9 mm HgD. 285.5 mm Hg

Answer» Correct Answer - A
`n_(CHCl_(3))=(25.5)/(119.5)=0.213`
`n_(CH_(2)Cl_(2))=(40)/(85)=0.47`
`P_(T)=P_(A)^(@)X_(A)+P_(B)^(@)X_(B)`
`=200xx(0.213)/(0.683)+41.5xx(0.47)/(0.683)`
`=62.37+28.55=90.92`


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