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The `Z_(eff)` for 3d electron of `Cr` `4s` electron of `Cr` `3d` electron of `Cr^(3+)` `3s` electron of `Cr^(3+)` are in the order respectivelyA. 4.6,2.95,4.95,8.05B. 4.95,2.95,4.6,8.05C. 4.6,2.95,5.3,16.55D. none of these |
Answer» Correct Answer - C `[C_(r) = 1s^(2) 2s^(2) 2p^(6) 3s^(2)3p^(6) 4s^(1) 3d^(5)` `Z_(eff) =` Atomic no `sigma` s for 4s electron (valence shell `e^(-) -1) xx 0.35 +` Penultimate shell `e^(-) xx 0.85 + `remaining `e^(-)` `= (1-1) xx 0.35 +13 xx 0.85 +10` `= 0 + 11.05 +10 = 21.05` `Z_(eff) = 24 - 21.05 = 2.95` `Z_(eff)` for 3d electron `sigma` for `3de^(-) =` (valence shell `e^(-)-1) xx 0.35 +` remaining `e^(-)` `= (5-1) xx 0.35 +18` `= 1.4 +18 = 19.4` `24 - 19.4 = 4.6]` |
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