1.

Theorderof decreasingnegativeelectrongainenthalpyof O. S, Se, is

Answer»

`O GT SGT SE`
`S gt O gt Se`
`Se gt O gt S`
`S gt Se gt O`

Solution :As the size ofthe atomincreasesdown agroup ,the negativeelectron gainenthalpydecreasesfromtop to bottom . Howeverdue tosmallsize theinter- electronicrepulsionsin the Oatom areso strongthat negativeelectrongain of O is the smallestamong theelementsof group16. Thusthenegativeelectrongainenthalpy of O, Sand Sedecreasesin theorder : `S gt Se gt O,` i.e.,OPTION(d) is correct.


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