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Tl(OH)_3 is less basic than TlOH. Why ? |
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Answer» SOLUTION :`Tl(OH)_3` is less basic than TLOH, as the polarising power of `Tl^(3+)` is more than `Tl^(1+)`. `Tl-O` BOND in `Tl(OH)_3` becomes STRONGER than that in `TlOH.` As Tl-O bond becomes stronger, release of `OH^(-)` ion becomes less POSSIBLE. Hence basic nature of `Tl(OH)_3` is less. |
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