1.

To neutralise completely 20 mL of 0.1M aqueous solution of phosphorus acid (H_3PO_3), the volume of 0.1 M aqueous KOH solution required will be ?

Answer»

10 mL
20 mL
40 mL
60 mL

Solution :`H_(3)PO_(3)` is a dibasic acid and ionises as follows:
`H_(3)PO_(3) 2-)`
KOH is a monoacid base. Hence,
0.1 M KOH = 0.1 N KOH
`0.1 M H_(3)PO_(3) = 0.2 N H_(3)PO_(3)`
`underset(KOH)(N_(1)V_(1)) = underset(H_(3)PO_(3))(N_(2)V_(2))`
`0.1 XX V_(1) = 0.2 xx 20`
or `V_(1) = 40 mL`


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