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Transition metal and their compounds are used as catalyst in Industry and in biological system for example in the contact process vanadium compounds in the `+5` state `V_(2)O_(5)` and `VO_(3)^(-)` are used to oxidise `SO_(2)` to `SO_(3)` `SO_(2) + 1/2 O_(2) overset(V_(2)O_(2))rarr SO_(3)` It is thought that the actual oxidation process takes place in two stages. In the first step `V^(+5)` in the presence of oxide ions converts `SO_(2)` to `SO_(3)`. At the same time `V^(+5)` is reduced to `V^(+4)` `2V^(+5) + O^(-2) + SO_(2) rarr 2V^(+4) + SO_(3)` In the second step `V^(+5)` is regenerated from `V^(+4)` by oxygen `2V^(+4) + 1/2 O_(2) rarr 2V^(+5) + SO_(3)` The overall process is of course the sum of these two steps. `SO_(2) + 1/2 O_(2) rarr SO_(3)` Catalytic activity of transition metals depends onA. Their ability of exist in different oxidation stales.B. The size of metal atomsC. The number of empty atomic orbitals availableD. None of these. |
| Answer» Correct Answer - A | |