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Two 5 molal solutions are prepared by dissolving a non-electroylete, non -volatile solute separately in the solvents X and Y. The molecular weights of the solvents are M_(x) and M_(Y), respectively where M_(X)=4/3M_(Y). The relative lowering of vapour pressure of the solution in X is "m" times that of the solution in Y. Given that the number of moles of solute is very small in comparision to that of solvent, the value of "m" is : |
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Answer» <P>`3/4` Number of moles of `=5xx1=5` (in both in solvents) Number of moles of solvent `x=1000/(M_(x))` Number of moles of solvent `Y=1000/(M_(Y))` Relative lowering in vapour pressure is GIVEN as `(p^(@)-p_(s))/(p_(s))=(n_(2))/(n_(1))` `((p^(@)-p_(s))/(p_(s)))_("solution in X")=5/(1000/M)=(5M_(x))/1000` `((p^(@)-p_(s))/(p_(s)))_("solution in Y")=5/(1000/(M_(Y)))=(5M_(x))/1000` According to question `1/mxx(5M)/1000=(5M_(Y))/1000` `1/mxx5xx3/4M_(Y)=M_(Y)` (Given `M_(x)=3/4M_(Y)"":.m=3/4` |
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