1.

Two containers of equal volume contain the same gas at pressures P_(1) and P_(2) and absolute temperatures T_(1) and T_(2) respectively. On joining the vessels, the gas reaches a common pressure Panda common temperature T. Find the value P/T.

Answer»

Solution :Number of moles before JOINING =
Number of mo]es after joining the vessels.
`n_(1) + n_(2) = n_(1)^(1) n_(2)^(1)`
i.e., `(P_(1)V)/(RT_(1)) + (P_(2)V)/(RT_(2)) = (PV)/(RT) + (PV)/(RT) `
(or) `(P_(2)V)/(RT_(1)) + (P_(2)V)/(RT_(2)) = (2PV)/(RT) `
`rArr (P_(1))/(T_(1)) + (P_(2))/(T_(2)) = (2P)/(T) "" therefore (P)/(T)= (1)/(2) [ (P_(1))/(T_(1)) + (P_(2))/(T_(2)) ] `


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