1.

Two important physical evidences supporting the synergic bonding in non-classical complexes are bond lengths and vibrational spectra. Vibrational spectra is based on the fact that the compression and extension of a bond may be analogous to the behaviour of a spring and obeys Hook's law. overline(v)=(1)/(2pic)sqrt((k)/(mu))cm^(-1) where, k=force force constant of the bond which is directly proportional to bonnd strength of CO mu=reduced mass of ligand overline(v)=stretching frequency of the CO bond c=velocity of light Q. In Mn_(2)(CO)_(10) carbonyl complex, the d-orbital of Mn-atom which can not be involved in synergic bonding betwee Mn and CO ligands:

Answer»

`d_(xz)`
`d_(XY)`
`d_(YZ)`
none of these

Solution :As `d_(xy)` forms `DELTA`-bondin `Mn_(2)(CO)_(10)`


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