1.

use the following data to calculate Delta_(" lattice")H^(@) for NaBr . Delta("sub")H^(-) fpr sodium metal = 108 .4 kJmol^(-1)lonisation enthaply of sodium = 496 kJ mol^(-1) ltbr gt Electron gain enthalpy of bromine =325 kJ mol ^(-1) bond dissociation enthalpy of bromine =192 kJ mol ^(-1) Delta_(t)H^(-)for NaBr (s) = -360 .1 kJ mol ^(-1)

Answer»

`-735.5 kJ mol^(-1)`
`+735.5kJ mol ^(-1)`
`-789.89 JK^(-1)mol ^(-1)`
`+735 . 5 J mol ^(-1)`

Solution :By applying Hess's law
`Delta_(F)H^(Theta)=Delta_("sub")H^(@)+lE+Delta_(diss)H^(@)+Delta_(EQ)H^(@) +U`
`-360.1 = 108.4 + 496 + 96 +(-325)+U`
` U =+ 735.5 kJ mol^(-1)`


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