1.

Using curved-arrow notation, show the formation of reactive intermediates when the following covalent bonds undergo heterolytic cleavage. (a) CH_(3) - SCH_(3), (b) CH_(3) - CH, (c ) CH_(3) - Cu

Answer»

Solution :(a) Bonding electron pair transfer on more negative S.

(b) The sp carbon of `C -=` is more negative then `H_(3)O (sp^(3))`.

(c ) In COMPARE to ELECTROPOSITIVE Cu metal, the negativecarbon atom ACCEPT bonding electron pair


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