1.

Using the data given below, calculate the value of equilibrium constant for the reaction. underset("Acetylene")(3HC-=CH(g)) hArr underset("Benzene")(C_(6)H_(6)(g)) at 298 K , assuming ideal gas behaviour. Delta_(f)G^(@)for HC-= CH(g) = 2.09 xx 10^(5) J mol^(-1),Delta_(f)G^(@)forC_(6)H_(6)(g) =1.24xx 10^(5) J mol^(-1) R = 8.314 J K^(-1) mol^(-1) Based on your calculated value, comment whether this process can be recommended as a practical method for making benzene.

Answer»


Solution :`Delta_(r) G^(@) =Delta_(f)G^(@) (C_(6)H_(6)) - 3 Delta_(f)G^(@)(HC -= CH) = 1.24 xx 10^(5) - 3 ( 2.9 xx 10^(5)) J = - 5.03 xx 10^(5)J`
`Delta_(r)G^(@) = - 2.303 RT LOG K `. Calculate K
`DELTA _(r)G^(@) ` is negative and K is very high . Hence, the PROCESS can OCCUR easily.


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