1.

Using the ideal gas equation how will you calculate the values of R ?

Answer»

Solution :We can calculate R using the equation,
`R=(PV)/(nT)`
(i) P is 1 atm, volume `22.414 md^(3)`. For 1 OLE at 273.15 K.
`R=(1 atm xx22.414 md^(3))/(1 "mol"xx273.15 k)`
`=0.0821 dm^(3) atm. "mol"^(-1)K^(-1)`
(II) (STP),
Where `P=1 "bar" (10^(5)` pascal)
`V=22.71xx10^(-3)m^(3) ` for 1 mole of gas at `273.15K`
`R=(10^(5)Px xx22.71xx10^(-3)m^(3))/(1 "mol"xx273.15K)`
`=8.314 Pam^(3) K^(-1) "mol"^(-1)`
`=8.314xx10^(-2) "bar" m^(3) K^(-1) "mol"^(-1)`
`=8.314xx10^(-2) "bar" dm^(3)K^(-1) "mol"^(-1)`
`=8.314xx10^(-2) bar LK^(-1)"mol"^(-1)`
`=8.314 J K^(-1) "mol"^(-1)`


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