1.

What are boranes ? Give chemical equation for the preparation of diborane.

Answer»

SOLUTION :Boranes are the binary compounds of boron and hydrogen like an Alkanes. These are covalent hydrides of formula `B_2H_6` called diborane.
PREPARATION of diborane : It is prepared by treating boron trifluoride with `LiAlH_4` in diethyl ETHER.
`4BF_3 + 3LiAlH_4 to 2B_2H_6 + 3LiF + 3AlF_3`
`B_2H_6` is produced on an industrial scale by the REACTION of `BF_3` with NaH (Sodium HYDRIDE)
`2BF_3 + 6NaH overset"450 K"to B_2H_6 + 6NaF`


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