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What are the key ideas of MO theory? OR What are the salient features of MO theory?

Answer»

Key ideas of MO Theory :

  • MOs in molecules are similar to AOs of atoms. Molecular orbital describes region of space in the molecule representing the probability of an electron.
  • MOs are formed by combining AOs of different atoms. The number of MOs formed is equal to the number of AOs combined.
  • Atomic orbitals of comparable energies and proper symmetry combine to form molecular orbitals.
  • MOs those are lower in energy than the starting AOs are bonding MOs and those higher in energy are antibonding MOs.
  • The electrons are filled in MOs beginning with the lowest energy.
  • Only two electrons occupy each molecular orbital and they have opposite spins, that is, their spins are paired.
  • The bond order of the molecule can be calculated from the number of bonding and antibonding electrons.


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