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What characteristics do you expect from an electron deficient hydride with respect to its structure and chemical reaction? |
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Answer» Solution :It is EXPECTED to be a Lewis acid. For example, DIBORANE `B_(2)H_(6) (DIMER of BH_(3))` forms a complex with LIH which gives `H^(-)` ion (Lewis base) `underset("LITHIUM hydride")(2LiH)+`underset("Diborane")(B_(2)H_(6)) to `underset("Lithium borohydride")(2Li^(+)[BH_(4)]^(-))` Similarly, it also combines with trimethuylamine (organinc compound) and carbon monoxide which act as Lewis base to form addition compound. `B_(2)H_(6)+underset("Trimethylamine")((CH_(3))_(3)) ddot(N) to underset("Addition compound")(2H_(3)B) leftarrow N(CH_(3))_(3)` `B_(2)H_(6)+CO to underset("Addition compound")((2H_(3)B) leftarrow CO` |
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