1.

What is [Ag^(+) ]in a solution made by dissolving both Ag_2 CrO_4 and Ag_2C_2O_4 until saturation is reached with respect to both salts ?[K_(sp)(Ag_2C_2O_4) =2xx 10 ^(-11), K_(sp)(Ag_2CrO_4) - 2xx10 ^(-12))]

Answer»

` 2.80 xx 10^(-4)`
` 7. 6 xx 10^(-5) `
` 6.63 xx 10^(-6)`
` 3 .52 xx 10 ^(-4) `

Solution :` Ag_2CrO_4 hArr 2Ag^(+) +CrO_4^(_2) `
` "" 2X+2Y"" x`
` Ag_2 C_2O_4hArr 2Ag^(+) C_2O_4^(-2)`
` "" 2y+2x"" y`
` (K_(s_(p1)))/(K_(s_(p2)))=(x)/(y)=(2xx 10^(-12))/(2xx 10^(-11)) =0.1`
` 2xx 10 ^(-11) =(2x + 2y)^(2) .y`
` 2 xx 10^(-11)=4.89 y^(3) `
` "" y= 1.6 xx 10^(4)rArr x= 0.16 xx 10^(-14) `
Total ` [AG^(+) ]=2x +2y =3.52 xx 10 ^(-4)`


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