1.

What is corrosion? Write the chemistry behind the formation of rust

Answer»

(i) The slow and steady destruction of a metal by chemical

or electro chemical reaction with the environment. 

(ii) When the surface of iron is exposed to moisture and other gases present in the atmosphere, the following chemical reaction takes place. 

Fe → Fe2+ + 2e- 

O2 + 2H2O + 4e- → 4OH- 

O2 + 4H+ + 4e- → 2H2

The Fe2+ ions are oxidised to Fe3+ ions.

The Fe3+ ions combine OH- ions to form Fe(OH)3 . This becomes rust which is hydrated ferric oxide with the formula Fe2O3.xH2O. It is a reddish brown substance.



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