1.

What is crystal field splitting energy?

Answer»

1. In an octahedral complex, the d – orbitals of the central metal ion divide into two sets of different energies. The separation in energy is the crystal field splitting energy. 

2. The d orbitals lying along the axes dx2 , dy2 and dz2 orbitals will experience strong repulsion and raise in energy to a greater extent than the orbitals with lobes directed between the axes (dxy , dyz and dzx ). Thus the degenerate d – orbitals now split into two sets and the process is called crystal filled splitting.



Discussion

No Comment Found