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What is crystal field stabilization energy (CFSE) ? |
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Answer» <P> Solution :The crystal field stabilisation energy is DEFINED as the energy difference of electronic configuration in the ligand field `(E_(LF))` and the isotropic field (Eiso).`CFSE(DeltaE_(0))={E_(LF)}-{E_(iso)}` `={[n_(t_(2g))(-0.4)+n_(e_(g))(0.6)Delta_(0)+n_(p)P}-{n._(p)P}` Here `n_(t_(g))` is the number of electrons in `t_(2g)` orbitals `n_(e_(g))` is the number of electrons in `e_(g)` orbitals `n_(p)` is the number of electrons in the ligand field `n._(p)` is the number of electrons in the isotropic field |
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