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What is peroxide effect?​

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Illustrated GLOSSARY of Organic Chemistry - PEROXIDE effect. Peroxide effect: The change in regioselectivity of the addition of HBr to an alkene or alkyne in the presence of a peroxide. ... In the absence of a peroxide, HBr adds to propene VIA an ionic MECHANISM (with a carbocation INTERMEDIATE) to give 2-bromopropane



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