1.

What is polymerisation? Explain the two types of polymerisation reaction of acetylene.

Answer»

Solution :A polymer is a large molecule formed by the COMBINATION of large number of small MOLECULES (monomers). This process is known as polymerisation. Acetylene UNDERGOES two TYPES of polymerisation reactions, they are: (Linear polymerisation (1) Cyclic polymerisation (1) Linear polymerisation: Acetylene forms linear polymer, when passed into a solution of cuprous chloride and ammonium chloride.
`underset("(Acetylene)")(2CH -=CH)overset(Cu_2Cl_2)underset(NH_4Cl)rarrCH_2=underset("(Vinyl acetylene)")underset(C-=CH)underset(|)"CH"`
(ii) Cyclic polymerisation: Acetylene undergoes cyclic polymerisation on passing through red hot iron TUBE. Three molecules of acetylene polymerises to form benzene.


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