1.

What is the effect of the following ionisation process on the bond order of O2 ?O2 \(\rightarrow\)  O2+ + e-

Answer»

O2 O2+ + e-

O2 = (16e-) is KK (σ2s)2(σ*2s)22pz)22px)2

= (π2py)2(π*2px)1(π*2py)1

Bond order = \(\frac{1}{2}\)(10 - 6) = \(\frac{4}{2}\) = 2

O2+ = (15e-) KK (σ2s)2( σ*2s)2( σ2pz)22px)2

= (π2py)2(π*2px)1

Bond order = \(\frac{1}{2}\)(10 - 5) = \(\frac{5}{2}\) = 2.5

Thus, bond order of O2 which is 2, increases to 2.5 in \(O_2^+\).



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