1.

What is the magnetic character of the anion of Na2O2?

Answer»

The anion of Na2O2 is O22− (peroxide ion)

Electronic Configuration –

8O = 9 = 2,7 = 1s2 , 2s22p5

8O = 9 = 2,7 = 1s2 , 2s22p5

Molecular Orbital Configuration

(σ1s)2 , (σ1s)2 , (σ2s)2 , (σ*2s)2 , (σ2pz)2 , (π2px)2 = (π2py)2(π*2px)2 = (π22py)2 , (σ*2pz)0

Since, there is no unpaired electron present in molecular orbital, so it diamagnetic in nature.



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