1.

What is the maximum concentration of Mg^(+2)that can be introduced into a solution containing0.1 M NH_3 and 0.01 M NH_4^(+ )without causing precipitation of Mg (OH)_2 ?K_b of NH_3 = 10^(6)K_(sp)of Mg(OH)_2 =1.2 xx 10^(-12)

Answer»

` 0.012 M`
` 0.24 M`
` 0.024 M`
` 0.048 M`

Solution :no Mg ` OH)_2 ` PPT
`rArr IPlt KSP rArr [Mg^(+2) ] [OH^(-)] ^(2) LT 1.2 XX 10 ^(_12) `
` [OH^(-) ] =(K_bxx [NH_3])/([NH_4^(+) ])=(10 ^(-6)xx 0.1)/( 0.01)= 10 ^(-5) `
` rArr [Mg^(+2) ] lt(1.2xx 10 ^(-12))/( 10 ^(-10) )= 1.2 xx 10^(-2) `


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