1.

What is the oxidation state of sulphur in (NH_(4))_(2)S_(2)O_(8) ?

Answer»

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Solution :(i) `(NH_(4))_(2)S_(2)O_(8)` It has `2NH_(4)^(+)andS_(2)O_(8)^(2-)` IONS.
(ii) `S_(2)O_(8)^(2-)` has one peroxy - O - O - BOND in which two oxygen atoms are in (-1) state, Remained six .O. atoms have -2 oxidation number.
`therefore2S+2(O)+6(O)=-2`
`therefore2x+2(-1)+6(-2)=-2`
`therefore2x-2-12=-2`
`therefore2x=+12`
`thereforex=+6`

The two .O. atoms have (-1) oxidation number


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