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What is the pH of 0.01M glycine solution ? For glycine K_(a_(1))=4.5xx10^(-3) and K_(a_(2))=1.7xx10^(-10) at 398 K

Answer»

`3.0`
`10.0`
`6.1`
`7.2`

Solution :Glycine `H_(3)N^(+)CH_(2)CO O^(-)` is more acidic than basic. Instead of `K_(b)` value, the SECOND given `K_(a)` value is corresponding to the `K_(b)` value `(.:' K_(a)xxK_(b)=10^(-14))`.Hence, OVERALL IONIZATION constant,
`K_(a_(1))xxK_(a_(2))=4.5xx10^(-3)xx1.7xx10^(-10)`
`=7.65xx10^(-13)`
`[H^(+)]=sqrt(KC)=sqrt(7.65xx10^(-13)xx0.01)`
`=sqrt(0.765xx10^(-14))=0.87xx10^(-7)M`
`pH = - log (0.87xx10^(-7))=7-0.93=6.07`


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