1.

What is the thermodynamic product obtained from the addition of 1 mole of HBr to 1,3-butadiene?

Answer»

1-bromo-2-butene
3-bromo-1-butene
4-bromo-1-butene
3-bromo-2-butene

SOLUTION :3-Bromo-1-butene is the kinetic product formed upon reaction of HBr with 1,3-butadiene It is formed by ADDITION of bromide anion to the resonance STABILIZED allylic carbocation formed by protonation of the diene. HOWEVER, there is a more STABLE isomeric product which is the thermodynamic product.


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