1.

What percentage of Fe+3 is present in Feo.0.93

Answer»

In pure iron oxide (FeO), iron and oxygen are present in the ratio 1 : 1.

However, here number of Fe2+present = 0.93

Or No. of Fe2+ions missing = 0.07

Since each Fe2+ion has 2 positive charge, the total number of charge due to missing (0.07) Fe2+ions = 0.07 * 2 = 0.14

To maintain electrical neutrality, 0.14 positive charge is compensated by the presence of Fe3+ions. Now since, replacement of one Fe2+ion by one Fe3+ion increases one positive charge, 0.14 positive charge must be compensated by the presence of 0.14 Fe3+ions.

In short, 0.93 Fe2+ions have 0.14 Fe3+ions

100 Fe2+ions have = 0.14/0.93 * 100 =15.05%



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