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What should be the ratio of concentration of acetic acid to sodium acetate while preparing an acid buffer mixture with pH = 5.7? (K_(a) for acetic acid is 1.8xx10^(-5)) |
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Answer» Solution :`pK_(a)=-logK_(a)` = `-log1.8xx10^(-5)` = +4.6447 `pH=pK_(a)+"log"(["Salt"])/(["Acid"])` `5.7=4.7447+"log"(["Salt"])/(["Acid"])` `"log"(["Salt"])/(["Acid"])=5.7-4.7447=0.9553` `(["Salt"])/(["Acid"])="ANTI"log0.9553=9.02~~9` `therefore` Ratio of concentration of acid : salt = 1 : 9 |
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