1.

What volume at S.T.P is occupied by (i) 3.50 g of nitrogen? (ii) 6.022 xx 10^(21)molecules of ammonia? (iii) 0.350 moles of oxygen? (iv) 39.9 g of argon?

Answer»

Solution :(i) The NUMBER of moles in 3.50 g of nitrogen
`=(3.50)/(28.02) = 0.125`
(since, the gram molecular mass of `N_(2)` is 28.02 g)
`therefore` One mole of a gas occupies 22.4 L at S.T.R
`therefore` Thevolumeoccupiedby0.125moles =` 0.125 xx 22.4 = 2.80 L`

Hence, 3.50 g of N2 occupy a VOLUME of 2.80 litres at S.T.P Ans.
(ii) One mole of a gas has 6.022 x 10 MOLECULES and occupies a volume of 22.4 L at S.T.P.
`therefore` The volume occupied by `6.022 xx 10^21` molecules.
(III) The volume occupied by 0.350 moles of `O_(2)` at S.T.P. = `0.350 xx 22.4 = 7.84` L (because the volume occupied by one mole at S.T.P. is 22.4 L)
Hence, 0.350 moles of `O_(2)` occupy 7.84 litres at S.T.P. Ans.
(iv) Argon is monoatomic in nature.
`therefore` 1 gram mole of Ar = 1 g atom of Ar = 39.95 g Hence, 39.95 g (1 mole) of argon will occupy a volume of 22.4 L at S.T.P.


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