1.

What will be the heat change at constant volume for the reaction whose heat change at constant pressure is -560 kcal at 27^(@)C? The reaction is C_(8)H_(16) + 12O_(2) to 8CO_(2) + 8H_(2)O (Given R = 2 cal mol^(-1)K^(-1))

Answer»

`-557600` calories
`442800` calories
`-561800` calories
`368240` calories

Solution :`DeltaH = -560 kcal, DELTAU = ?`
`C_(8)H_(16)(l) + 12O_(2)(g) to 8CO_(2)(g) + 8H_(2)O(l)`
`DeltaH = DeltaU + Deltan_(g) RT`
`Deltan_(g) = 8 -12 = -4`
`-560000 = DeltaU + (-4) xx 2 xx 300`
= `-557600`.


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