1.

What would be the expected product of the reaction of propyne with Br_2//H_2O if the mechanism of this reaction is analogous to that of of propene ?

Answer»

2-Bromopropenol
Bromoacetone
2-Bromo-2-propanol
Bromoprophenol

Solution :During addition of `Br_2//H_2O` , FIRST `Br^+` adds FOLLOWED by nucleophilic ATTACK by `H_2O`. LOSS of a `H^+` followed by tautomerization gives 2-bromoacetone.


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