1.

Whatismeant by entropy drivenreaction? How can the reaction with positivechange of enthalpy and entropydriven?

Answer»

Solution :The free energy change of a reaction is GIVEN by `DeltaG = DeltaH -TDELTAS`
For a reaction to be SPONTANEOUS, `DeltaG` shouldbe `-ve`.
If both `DeltaH`and `DeltaS` are positive, `DeltaG` can be`-ve` if `T Delta Sgt DeltaH`in magnitudee. Thus, entropy factor should dominate over enthalpyfactor. Such reactions are therefore, called entropy driven.This canhappen in either of the following two WAYS `:`
(i) `DeltaS` shoul beso learge that even if T is low , `T DeltaS` should be GREATER than`DeltaH`
(ii) If` DeltaS`is small, T should be so large that`T DeltaSgt DeltaH`


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