1.

When 10 g C2H5OH(I) are formed, 51 kJ heat is liberated. Calculate standard enthalpy of formation of C2H5OH(I).

Answer»

Given : 

Mass of C2H5OH(I) = m = 10 g

Heat liberated = ΔH1 = -51 kJ

Molar mass of C2H5OH = 46 gmol-1

Standard enthalpy of formation of C2H5OH(I)

= ΔfH = ?

Standard enthalpy of formation is the enthalpy change for the formation of 1 mole C2H5OH(I) 

i.e., 46 g C2H5OH(I).

Now,

∵ For the formation of 10 g C2H5OH(I)

ΔH1 = -51 kJ

∴ For the formation of 46 g C2H5OH,

ΔfH0\(\frac{-51\times 46}{10}\) = – 234.6 kJ mol-1

∴ Standard enthalpy of formation of C2H5OH

= ΔfH0 = – 234.6 kJ mol-1



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