1.

When 2s orbital overlaps with 2p_(x) or 2p_(y) orbital (assuming Z-axis as the internuclear axis ), there is a partial overlap , yet they don't form any molecular orbital.Explain why.

Answer»

SOLUTION :This is bacause 2s ORBITAL weve function has same SIGN throughout but `2p_(x) or 2p_(y)`orbital weve function
has + ve sign in one lobe and -ve sign in the other lobe. The SMALL ++ overlap cancels the +- overlap which
being equal in area but opposite in sign


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