1.

When a current of 0.75 A is passed through `CuSO_(4)` solution of 25 min, 0.369g of copper is deposited at the cathode. Calculate the atomic mass of copper.

Answer» Quantity of electricity passed `=(0.75A)(25xx60s)=1125C`
`Cu^(2+) to 2e^(-)toCu`
Thus, 1 mole of Cu (i.e., gram atomic mass) is deposited by 2F, i.e, `2xx96500C`
Now, `1125` C deposit Cu=0.369 g
`2xx96500C` will deposit Cu=`(0.369)/(1125)xx2xx96500g=63.3g`
hence, atomic mass of copper=63.3


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