1.

When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of aqueous NH_(3) dissolves. O and gives an intense blue solution QThe final solution contains

Answer»

`[PB(NH_(3))_(4)]^(2+)and[CoCl_(4)]^(2-)`
`[Al(NH_(3))_(4)]^(3+)`and`[Cu(NH_(3))_(4)]^(2+)`
`[Ag(NH_(3))_(2)]^(+)`and`[Cu(NH_(3))4_()](2+)`
 `[Ag(NH_(3))_(2)]^(+)` and `NI(NH_(3)_(6)]^(2+)`

Solution :`underset(N)(AgNO_(3))+NaCl tounderset(O)(AGCL)downarrow+NaNO_(3)`
`AgCl+2NH_(3)to[Ag(nH_(3))_(2)]^(+)]Cl^(-)`
Cu(NO_(3))_(2)+4NH_(4)OHto{Cu(NH)_(3))_(4)]^(2+)`


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