1.

When a sample of a gas is compressed at constant temperature from 15 atm to 60 atm, its volume changes from 76 cm^3 to 20.5 cm^3. Which of the following are possible.

Answer»

The gas SHOWS non-ideal behaviour
The gas dimerizes
The gas is adsorbed onto the vessel walls
The gas molecules have REPULSIONS to each other

Solution :`P_1V_1 = 15 xx 76 = 1140`
`P_2V_2 = 60 xx 20.5 = 1230` = non ideal behavious
If it was ideal, `V_2 = 19`
`= V_r > V_i = Z > 1 = ` repulsions dominate.


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