1.

When a substance has completed a cycle v, u, h and s are unchanged. Did anything happen? Explain. 

Answer»

Yes

During various parts of the cycle work and heat transfer may be transferred. That happens at different P and T. The net work out equals the net heat transfer in (energy conservation) so dependent upon the sign it is a heat engine or a heat pump (refrigerator). The net effect is thus a conversion of energy from one storage location to another and it may also change nature (some Q got changed to W or the opposite) 



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