1.

When an electron in an excited state of Mo atom falls from L to K-shell, an X-ray is emitted. These X-rays are diffracted at angle of 7.75^@ by planes with a separation of 2.64 Å. What is the difference in energy between K-shell and L-shell in Mo, assuming a first order diffraction ? (sin 7.75^@ =0.1349)

Answer»

Solution :According to BRAGG's equation :
`n lambda =2 d SIN theta`
`1 xx lambda=2xx2.64 sin 7.75^@ =2xx2.64 xx0.1349`
`lambda`=0.712 Å
Energy DIFFERENCE between K and L-shell of Mo=`"hc"/lambda=(6.626xx10^(-34)Js xx 3xx10^8 MS^(-1))/(0.712xx10^(-10)m)`
`=2.791xx10^(-15) J`


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