1.

When any solution passes through a cation exchange resin that is in acidic form, H^(+) ion of the solution. A solution containing 0.319 g of an isomer with molecular formula CrCl_(3).6H_(2)O is passed through a cation exchange resin in acidic form. The diluted solution requires 19cm^(3) of 0.125 N NaOH. The isomer is :

Answer»

triaquatrichlorochrominum (III) chloride trihydrate
hexaaquachromium (III) chloride
pentaaquamonochlorochromium (III) chloride monohydrate
tetraaquadichlorochromium (III) chloride dihydrate

Solution :`CrCl_(3).6H_(2)Oto` diluted solution requires 19 mm and 0.125N NaOH=2.375 m mole `OH^(-)`
`0.319/266.5 = 0.00119`
`CrCl_(3).6H_(2)O to 0.00119` mole,
`[Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)Oto 2CL^(-)to 2H^(+)`
`2H^(+)` requires `to 2OH^(-)`
`0.00119 xx 2` MOLES of `Cl^(-1)=nH^(+)`
`1000 xx 0.00238`=2.38 moles


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