1.

When aqueous solution of borax is acidified with hydrochloric acid, a white crystalline solid is formed which is soapy to touch. Is this solid acidic or basic in nature ? Explain.

Answer»

Solution :An aqueous solution of borax is acidified with HCl to give boric acid.
`Na_2B_4O_7 + 2HCL + 5H_2O to 2NaCl + underset"Boric acid"(4H_3BO_3)`
Boric acid is a weak monobasic acid. It is not a protonic acid but acts as a Lewis acid by ACCEPTING ELECTRONS from a hydroxyl ion :
`B(OH)_3 + 2HOH to [B(OH)_4]^(-)+ H_3O^+`


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